Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling
Description
One-dimensional polymer chains consisting of π-conjugated porphyrin units are formed via Glaser coupling on a Ag(111) surface. Scanning probe microscopy reveals the covalent structure of the products and their ordering. The conformational flexibility within the chains is investigated via a comparison of room temperature and cryogenic measurements.
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Subjects
- Porphyrins
- Scanning tunneling microscopy
- Atomic force microscopy
- Surfaces
- Catalysis
- On-surface synthesis, Porphyrin polymers, Scanning tunelling microscopy, STM, non-contact atomic force microscopy, ncAFM, Surfaces, Catalysis
- Physical sciences::Chemistry::Physical chemistry
- Physical sciences::Physics::Chemical physics, Solid-state physics
- Q Science::QD Chemistry::QD450 Physical and theoretical chemistry
Divisions
- University of Nottingham, UK Campus::Faculty of Science::School of Physics and Astronomy
Deposit date
2016-06-29Data type
Scanning probe microscopy images (STM and AFM)Contributors
- Browning, Abigail
- Rahe, Philipp
- Anderson, Harry
- Beton, Peter
Funders
- Engineering & Physical Sciences Research Council
- People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme
Grant number
- EP/J006939/1
- 623992-TOPCHEM
- 628439-DECiMOL
Collection dates
- November 2015 - January 2016
Data collection method
Scanning Tunelling Microscopy (STM): Omicron STM-1 and Omicron LT STM/AFM systems. Atomic Force Microscopy (AFM): Omicron LT STM/AFM system.Resource languages
- en
Copyright
- University of Nottingham